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Spray Nine Citrus Blaster Bug & Tar Remover, Aerosol-11/15/2016-Old Product
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Preparation
Indicates country where product is sold.
Market: US/CanadaSpray Nine Citrus Blaster Bug & Tar Remover provides a bolt of true citrus power charged with 25 percent dÂ’limonene instantly dissolves and lifts away stubborn soils and contains no petroleum solvents.
Purpose of product.
Usage: Bug and tar remover.Structure such as solid, liquid, aerosol etc.
Form: aerosolDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: February 13, 20246875 Parkland Boulevard
Solon OH 44139
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
Advanced
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Percent of chemical in preparation.
% Conc.Chemical of Concern (CoC)
Chemical of Concern(CoC)d-Limonene 005989-27-5 10.0-20.0 Yes 
CoC List
Propane 000074-98-6 2.5-10.0 No Butane 000106-97-8 2.5-10 Yes CoC List
Sodium nitrite 007632-00-0 0.1-1.0 No -
Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Safety Data Sheet (SDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
View Safety Data Sheet(SDS) Date that the Safety Data Sheet (SDS) was issued by manufacturer of a specific product.
SDS DATE :November 15, 2016 Health Flammability Reactivity HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product.
HMIS RATING2 3 0 -
V.O.C Information
Volatile Organic Compounds %/Wt. With Solvent : 19.5
Measure of Alkalinity/Acidity of substance or preparation where a level of 7 is considered as neutral.
pH Levels7.6 -
Warnings
Hazard Statements
Danger. Causes skin irritation. May cause an allergic skin reaction. Extremely flammable aerosol. Contains gas under pressure; may explode if heated.
Precautionary Statements
Prevention
Avoid breathing dust/fume/gas/mist/vapors/spray. Wear protective gloves/protective clothing/eye protection/face protection. Wash face, hands and any exposed skin thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use.
Response
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse
Storage
Protect from sunlight. Do not expose to temperatures exceeding 50 deg C/122 deg F.
Disposal
Dispose of contents/container to an approved waste disposal plant. -
Acute health effects
From SDS:
Hazards Identification
Emergency Overview
Danger. Causes skin irritation. May cause an allergic skin reaction. Extremely flammable aerosol. Contains gas under pressure; may explode if heated
Potential Health Effects
Eye Contact: Contact with eyes may cause irritation. May cause redness and tearing of the eyes.
Skin Contact: May cause skin irritation and/or dermatitis. May cause sensitization by skin contact.
Inhalation: May cause irritation of respiratory tract.
Ingestion: Ingestion may cause irritation to mucous membranes.
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Chronic health effects
From SDS:
No information available. -
Carcinogenicity
d-limonene, CAS No 005989-27-5: IARC Listed Group 3Sodium Nitrite, CAS No 007632-00-0: IARC Listed Group 2A -
Handling information
Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Contents under pressure. Do not puncture or incinerate cans. Do not expose to temperatures exceeding 50 deg C/122 deg F. Keep from freezing.
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Disposal information
This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261).
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California Prop. 65 Warning
This product does not contain any Proposition 65 chemicals
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First Aid
Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.Skin Contact: Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash with soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse.Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician.Ingestion: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician.
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UN Global Harmonization Classification
